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Aqueous-Phase Asymmetric Transfer Hydrogenation of Ketones — A Greener Approach to Chiral Alcohols

✍ Scribed by Xiaofeng Wu; Jianliang Xiao

Publisher: John Wiley and Sons
Year: 2007
Weight: 11 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200742227

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## Abstract A highly efficient and enantioselective hydrogenation of unprotected β‐ketoenamines catalyzed with ruthenium(II) dichloro{(__S__)‐(−)‐2,2′‐bis[di(3,5‐xylyl)phosphino]‐1,1′‐binaphthyl}[(2__S__)‐(+)‐1,1‐bis(4‐methoxyphenyl)‐3‐methyl‐1,2‐butanediamine] {Ru[(__S__)‐xylbinap][(__S__)‐daipen]