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An Efficient Approach to Chiral Ferrocene-Based Secondary Alcohols via Asymmetric Hydrogenation of Ferrocenyl Ketones

✍ Scribed by Wing-Sze Lam; Stanton H. L. Kok; Terry T.-L. Au-Yeung; Jing Wu; Hong-Yee Cheung; Fuk-Loi Lam; Chi-Hung Yeung; Albert S. C. Chan


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
184 KB
Volume
348
Category
Article
ISSN
1615-4150

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## Abstract A highly efficient and enantioselective hydrogenation of unprotected β‐ketoenamines catalyzed with ruthenium(II) dichloro{(__S__)‐(−)‐2,2′‐bis[di(3,5‐xylyl)phosphino]‐1,1′‐binaphthyl}[(2__S__)‐(+)‐1,1‐bis(4‐methoxyphenyl)‐3‐methyl‐1,2‐butanediamine] {Ru[(__S__)‐xylbinap][(__S__)‐daipen]