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Chiral Induction Effects in Ruthenium(II) Amino Alcohol Catalysed Asymmetric Transfer Hydrogenation of Ketones: An Experimental and Theoretical Approach

✍ Scribed by Daniëlle G. I. Petra; Joost N. H. Reek; Jan-Willem Handgraaf; Evert Jan Meijer; Peter Dierkes; Paul C. J. Kamer; Johannes Brussee; Hans E. Schoemaker; Piet W. N. M. van Leeuwen

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 341 KB
Volume: 6
Category: Article
ISSN: 0947-6539
DOI: 10.1002/1521-3765(20000804)6:15<2818::aid-chem2818>3.0.co;2-q

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Amino Alcohol Coordination in Ruthenium(

Amino Alcohol Coordination in Ruthenium(II)-Catalysed Asymmetric Transfer Hydrogenation of Ketones

✍ Daniëlle G. I. Petra; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Kees Goubitz; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB 👁 2 views

The nature of ruthenium-amino alcohol precursors in the aminoethane (1) coordinates through two nitrogen atoms, was structurally characterised by X-ray diffraction (8). -catalytic cycle of asymmetric hydrogen transfer reactions was studied using two C 2 -symmetrical tetradentate ligands (1 and Based