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Aqueous and Solvent-Free Uncatalyzed Three-Component Vinylogous Mukaiyama–Mannich Reactions of Pyrrole-Based Silyl Dienolates

✍ Scribed by Andrea Sartori; Luca Dell'Amico; Claudio Curti; Lucia Battistini; Giorgio Pelosi; Gloria Rassu; Giovanni Casiraghi; Franca Zanardi

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 396 KB
Volume: 353
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201100572

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## Abstract The cyclic ether (I) reacts in the presence of PNO with a variety of aldehydes and ketones the give vinylogous aldols as masked δ‐hydroxy‐β‐ketoesters.