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ChemInform Abstract: anti-Selective, Catalytic Asymmetric Vinylogous Mukaiyama Mannich Reactions of Pyrrole-Based Silyl Dienolates with N-Aryl Aldimines.

✍ Scribed by Claudio Curti; Lucia Battistini; Beatrice Ranieri; Giorgio Pelosi; Gloria Rassu; Giovanni Casiraghi; Franca Zanardi

Publisher
John Wiley and Sons
Year
2011
Weight
42 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract The application of the chiral pyrrolidine based thiourea organocatalyst (PTU) produces the anti‐Mannich products in excellent yields as well as diastereo‐ and enantioselectivities.