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ChemInform Abstract: Solvent-Free Mukaiyama and Mukaiyama—Michael Vinylogous Reactions of a Dioxinone-Derived Silyl Enol Ether Promoted by Lewis Bases.

✍ Scribed by Arrigo Scettri; Vincenzo De Sio; Rosaria Villano; Patrizia Manzo; Maria Rosaria Acocella


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The cyclic ether (I) reacts in the presence of PNO with a variety of aldehydes and ketones the give vinylogous aldols as masked δ‐hydroxy‐β‐ketoesters.