In the title compound, [Cu(Cl~2~CHCO~2~)~2~(C~6~H~6~N~2~O)~2~(H~2~O)], both the Cu^II^ atom and the O atom of the coordinated water molecule lie on a crystallographic twofold rotation axis. The Cu^II^ atom is coordinated by O atoms from two monodentate chloroacetate anions, pyridine N atoms from two
Aquabis(chloroacetato-κO)bis(pyridine-κN)copper(II)
✍ Scribed by Sieroń, Lesław
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 190 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Cu(CH~3~CO~2~)~2~(C~9~H~7~N~3~O)~2~(H~2~O)], is a mononuclear complex in which the Cu^II^ atom assumes a square-pyramidal coordination geometry. The Cu atom and the aqua O atom lie on a crystallographic twofold rotation axis. In the crystal structure, there are hydrogen bonds an
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of
Single-crystal X-ray study T = 263 K Mean '(C±C) = 0.004 A Ê R factor = 0.033 wR factor = 0.079 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.