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Tetra-μ-methacryl­ato-κ8O:O′-bis­[(pyridine-κN)copper(II)]

✍ Scribed by Wu, Bin ;Wang, Guocheng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
226 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 263 K Mean '(C±C) = 0.004 A Ê R factor = 0.033 wR factor = 0.079 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Tetra­kis(μ2-2,2-dimethyl­propanoato-κ2O
✍ Blewett, Gavin ;Esterhuysen, Catharine ;Bredenkamp, Martin W. ;Koch, Klaus R. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

The title compound, [Cu 2 (C 5 H 9 O 2 ) 4 (C 5 H 5 N) 2 ], consists of centrosymmetric binuclear cage units with four dimethylpropanoate bridges linking the two Cu centres [CuÁ Á ÁCu = 2.6229 (9) A ˚]. The square-pyramidal Cu coordination is completed by a pyridine N atom at the apical site. Astack