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Aqua(azido)(μ-azido)bis{2-[(2-dimethylaminoethylimino)methyl]-6-methoxyphenolato}dicopper(II) monohydrate

✍ Scribed by Diao, Yun-Peng ;Li, Kun

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
770 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Cu 2 (C 12

consists of a dinuclear complex molecule and a solvent water molecule. One Cu atom is six-coordinated by the phenol O atom and by one imine and one amine N atoms from one Schiff base ligand, the phenol and ether O atoms of the second Schiff base, together with a terminal N atom of the bridging azide ligand, in an octahedral geometry. The coordination environment of the second Cu atom contains a phenol O and imine and amine N atoms from one Schiff base ligand, two further N atoms, one from the bridging and the other from a terminal azide ligand, and a coordinated water molecule, also in an octahedral geometry. The crystal structure involves O-HÁ Á ÁN and O-HÁ Á ÁO hydrogen bonds.

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