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Di-μ-azido-κ4N:N-bis­{aqua­[2-(2-pyridylmethyl­ideneamino)ethanesulfonato-κ3N,N′,O]nickel(II)} dihydrate

✍ Scribed by Li, Jia-Ming ;Jiang, Yi-Min ;Wang, Yan-Fei ;Liang, Da-Wen

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
450 KB
Volume
61
Category
Article
ISSN
1600-5368

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Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis
Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis­(2-pyridylmethyl-κN)ethyl­amine]manganese(II)}
✍ Qian, Jing ;Gu, Wu ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Cheng, Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II

Bis[2-(2-pyridylmethylamino)ethanesulfon
Bis[2-(2-pyridylmethylamino)ethanesulfonato-κ3N,N′,O]nickel(II)
✍ Liao, Bei-Ling ;Li, Jun-Xia ;Jiang, Yi-Min 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 985 KB

In mononuclear [Ni(C 8 H 11 N 2 O 3 S) 2 ], a nickel(II) complex of 2-(2-pyridylmethylamino)ethanesulfonic acid, the six-coordinate Ni atom lies on a centre of symmetry. The monodeprotonated anion coordinates in a facial arrangement through two N and one O atoms. Intermolecular N-HÁ Á ÁO hydrogen bo