Aqua[3,6-bis(methoxycarbonylmethyl)-3,6-diazaoctanedioato]copper(II) dihydrate
✍ Scribed by Esterhuysen, Catharine ;Bredenkamp, Martin W. ;van Kralingen, Leon ;Adendorff, Hanelie J. ;Jacobs, Edmund P. ;Swart, Pieter
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 266 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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Treatment of deprotonated N,N 0 -bis-(4-methyl-2-benzothiazolyl)-2,6-pyridicarboxamide (L 2À ) with CuCl 2 Á2H 2 O yields the mononuclear title complex, CuL(H 2 O) or [Cu(C 23 H 15 N 5 -O 2 S 2 )(H 2 O)]. The Cu II atom adopts a distorted square-planar coordination geometry, binding to two deprotona
10 0 0 00 0 0 -(4-Methoxybenzylidene)-5 0 0 00 0 0 ,4 0 0 0 -bis(4-methoxyphenyl)-1 0 0 0 -methyl-2,3,2 0 0 00 0 0 ,3 0 0 00 0 0 ,7 0 0 00 0 0 ,8 0 0 00 0 0 ,9 0 0 00 0 0 ,10 0 0 00 0 0 -octahydro-1H,5 0 0 00 0 0 H,6 0 0 00 0 0 H-indole-3-spiro-2 0 0 0 -pyrrolidine-3 0 0 0 -spiro-2 0 0 00 0 0 -cyclo
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.004 A R factor = 0.038 wR factor = 0.104 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.