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Approaches to the Fluorous Mitsunobu Reaction

✍ Scribed by Roman Dembinski


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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A Fluorous Phase Approach to Rhodium-Catalyzed Carbenoid Reactions with Diazoacetates. -The cyclopropanation of alkenes (I) with diazoacetate in the presence of Rh(II) carboxylates bearing perfluoroalkyl chains are described. The catalyst can be extracted into perfluoro(methylcyclohexane) and reused