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ChemInform Abstract: A Fluorous Phase Approach to Rhodium-Catalyzed Carbenoid Reactions with Diazoacetates.

✍ Scribed by Andreas Endres; Gerhard Maas

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199945089

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✦ Synopsis

A Fluorous Phase Approach to Rhodium-Catalyzed Carbenoid Reactions with Diazoacetates. -The cyclopropanation of alkenes (I) with diazoacetate in the presence of Rh(II) carboxylates bearing perfluoroalkyl chains are described. The catalyst can be extracted into perfluoro(methylcyclohexane) and reused without loss of activity.

-(ENDRES, ANDREAS; MAAS,

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