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Application of thin film dialysis to the determination of equilibrium constants

✍ Scribed by Salvatore F. Russo; Randall G. Engel

Publisher
Wiley (John Wiley & Sons)
Year
1978
Tongue
English
Weight
288 KB
Volume
17
Category
Article
ISSN
0006-3525

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✦ Synopsis

Synopsis

A theoretical basis for thin-film dialysis involving binding between a ligand and nondialyzing species is presented. A general differential equation that applies to the case of equivalent, noninteracting sites is derived relating [A]F, [A]T, [PIT, and K . Numerical solutions to this equation are used to develop a series of escape curves corresponding to specific values of the parameters [PIT, [A]i, K , and ko. A general method for determining an equilibrium binding constant from thin-film dialysis data is given. A comparison of thin-film dialysis results

predicted by this theory with literature data shows essential agreement.

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