The first (Z(l)) and second (Zc2)) approximations to the rotational collision number of the Ar-N2 system are compared for a range of temperatures Although Z(l) and Zt2) . differ by a significant amount their difference r& mains nearly constant as a function of temperature. The effects of mass and p
Application of the PHD approximation to the high rotational transitions in the Ar + N2 system
β Scribed by Michael Tamir; Moshe Shapiro
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 248 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The p-helicity&wupling (PHD) scheme is applied to high rotational transitions in the AI f Nz system and found to give more accurate cross sections and opacity functions than other known approximations. * hp the phelicity is defined as the projection of J on the direction of p -the linear momentum. Thus hP = J-p (=j'& while hR the R-helicity is AR = J-fi (= j-h). The phelicity representation uses the (J,M, i, A$ quantum numbers instead of the Arthurs and Dalgamo [ 121 (.I& j, r) representation.
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The jackknife test of Rothstein et al. is applied to discrimination between severaI different models used to compute the rotationally inelastic cross sections for the Ar-N2 system. The modified exponential models are the best models, except for the case where the energy gap is small, when power laws
A large number of rotational transitions of 32S16O2, 34S16O2, and 32S18O16O have been measured in the mm-, submm-, and terahertz ( approximately 1 THz) spectral regions. These data sets have been combined with all previously measured SO2 microwave and selected far infrared data to obtain a highly pr
Tltc prcscnt study introduces ;I simplified method for :rcating vibrational-rot;ltionnl coupling during the collisionnl cschan~e of energy. This rorationnl couplinp modifies the vibrational cncrgy mismatch, wo and is a dominant cffcct, working to make the actu;ll energy mismatch smtilcr than the app