The jackknife test of Rothstein et al. is applied to discrimination between severaI different models used to compute the rotationally inelastic cross sections for the Ar-N2 system. The modified exponential models are the best models, except for the case where the energy gap is small, when power laws
Rotational relaxation in the Ar—N2 system
✍ Scribed by Alan Gelb; Raymond Kapral
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 314 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The first (Z(l)) and second (Zc2)) approximations to the rotational collision number of the Ar-N2 system are compared for a range of temperatures Although Z(l) and Zt2) .
differ by a significant amount their difference r& mains nearly constant as a function of temperature. The effects of mass and potential parameter variations on the rotational rekation time are also studied. When the mass of the incoming atom is decreased Zt2) minimum while Z(l) steadily increases.
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