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Application of palladium ferrocenyl amine sulfide complexes in the hydrogenation of carbon—carbon double and triple bonds

✍ Scribed by Hussein M. Ali; Ahmad A. Naiini; Carl H. Brubaker Jr.

Publisher
Elsevier Science
Year
1992
Weight
520 KB
Volume
77
Category
Article
ISSN
0304-5102

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Selective reduction of carboncarbon double and triple bonds in conjugated olefins mediated by SmI2/H2O/amine in THF
✍ Anders Dahlén; Göran Hilmersson 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 137 KB

Conjugated double and triple bonds are reduced into alkenes using non-hazardous SmI 2 /H 2 O/amine mixtures as reducing agents in THF. Isolated alkenes are not reduced during these reductions. All the reactions studied are quantitative and are completed in less than five minutes.