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Formamides from carbon dioxide, amines and hydrogen in the presence of metal complexes

✍ Scribed by Peter Haynes; Lynn H. Slaugh; Josef F. Kohnle


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
227 KB
Volume
11
Category
Article
ISSN
0040-4039

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## Abstract With some common metal salts (CuI, FeCl~3~) as catalysts, alkynes can be effectively electrocarboxylated with CO~2~ (4 MPa) in an undivided cell with Ni cathode and Al sacrificial anode containing __n__‐Bu~4~NBr‐DMF as supporting electrolyte with a constant current at room temperature.