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Tailored Ruthenium–N-Heterocyclic Carbene Hybrid Catalytic Materials for the Hydrogenation of Carbon Dioxide in the Presence of Amine

✍ Scribed by Mathieu Baffert; Dr. Tarun K. Maishal; Laurent Mathey; Prof. Dr. Christophe Copéret ; Dr. Chloé Thieuleux

Publisher
Wiley (John Wiley & Sons)
Year
2011
Tongue
English
Weight
210 KB
Volume
4
Category
Article
ISSN
1864-5631

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Silica hybrid gel catalysts containing ruthenium complexes: influence of reaction parameters on the catalytic behaviour in the synthesis of N,N-dimethylformamide from carbon dioxide
✍ Oliver Kröcher; René A. Köppel; Alfons Baiker 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 198 KB

The synthesis of N,N-dimethylformamide from carbon dioxide, hydrogen and dimethylamine has been studied in an Ä Ž . Ž . 4 Ž . autoclave using a sol-gel derived heterogeneous catalyst made of RuCl PPh CH Si OEt and Si OEt in a ratio of 2 2 2 2 33 4 1:50. The effect of the reaction variables on the ac