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Selective reduction of carboncarbon double and triple bonds in conjugated olefins mediated by SmI2/H2O/amine in THF

✍ Scribed by Anders Dahlén; Göran Hilmersson

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 137 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00369-1

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✦ Synopsis

Conjugated double and triple bonds are reduced into alkenes using non-hazardous SmI 2 /H 2 O/amine mixtures as reducing agents in THF. Isolated alkenes are not reduced during these reductions. All the reactions studied are quantitative and are completed in less than five minutes.

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