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Application of Mitsunobu Reagents to Redox Isomerization of CF 3 -Containing Propargylic Alcohols to ( E )-α,β-Enones

✍ Scribed by Watanabe, Yohsuke; Yamazaki, Takashi

Book ID
120082957
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
840 KB
Volume
76
Category
Article
ISSN
0022-3263

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Cationic Rhodium(I)/Bisphosphane Complex
Cationic Rhodium(I)/Bisphosphane Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones
✍ Ken Tanaka; Takeaki Shoji; Masao Hirano 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to α,β‐enones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)‐BINAP