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Application of Electrospray Mass Spectrometry for Characterizing Supramolecular Coordination Complexes

✍ Scribed by Gérara Hopfgartner; Jack D. Henion; Claude Piguet; Alan F. Williams

Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
407 KB
Volume
76
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The Electrospray Mass Spectrometry (ES‐MS) of eight different supramolecular complexes shows that the molecular peaks of the desolvated multiply charged cations can be recorded more easily than by Fast‐Atom‐Bom‐bardment Mass Spectrometry (FAB‐MS) measurements of similar compound. The preliminary application of the ES‐MS technique to self‐assembled helical complexes obtained from ligands L^3^ to L^8^ with various metal ions (Cu, Co, Eu, Tb) indicates that ES mass spectra qualitatively reflect the species present MeCN solution.

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