Application of a calorimetric method in radiation-induced polymerizations—I Determination of propagation and termination rate constants for methyl methacrylate
✍ Scribed by G. Palma; L. Busulini; S. Lora
- Book ID
- 107753164
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 884 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0014-3057
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Abstraet--A study on the polymerization of n-butyl methacrylate has been performed using 6°Co 7-rays. The kinetics were followed by a calorimetric method already used with methyl-and ethyl-methacrylate. In this case also, the rate of polymerization was found to be proportional to (dose rate) i over
The gamma induced polymerizations of iso-butyl-(i-BMA) and dodecyl-(DDMA) methacrylates under non-stationary conditions have been studied, utilizing a calorimetric method already used for other methacrylates. For both monomers, the polymerization rate was found to vary linearly with (dose rate)½ at
A relatively fast method for determining the initial rate of polymerization from the maximum of isothermal thermograms ("Vp. max method") is described. The method was verified for the polymerization of methyl methacrylate in dimethylformamide. The initial rates and overall rate constants agree excel