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Antarafacial allylic participation in a thermal 1,3-sigmatropic carbon migration

โœ Scribed by Baldwin, John E.; Fleming, Ronald H.


Book ID
124168384
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
401 KB
Volume
94
Category
Article
ISSN
0002-7863

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A [3,4] Allyl Shift in a thermal rearran
โœ Bernard Miller; Welh-Oh Lin ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 119 KB

PQrations of ally1 p~ouos in acid catalyzed rearran~ments of cyclohexadienones give products resulting from [1,2], [1,3], [1,4], [1,5], [3,3], and [3,4] shifts.2 In contrast, only Cope and Claisen ([3,3]) mivations of ally1 \_g~ups have been observed in thermal rearrangements