A [3,4] Allyl Shift in a thermal rearrangement of a β-naphthalenone1

✍ Scribed by Bernard Miller; Welh-Oh Lin

• Book ID: 104237142
• Publisher: Elsevier Science
• Year: 1978
• Tongue: French
• Weight: 119 KB
• Volume: 19
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)85385-5

✦ Synopsis

PQrations of ally1 p~ouos in acid catalyzed rearran~ments of cyclohexadienones give products resulting from [1,2], [1,3], [1,4], [1,5], [3,3], and [3,4] shifts.2 In contrast, only Cope and Claisen ([3,3]) mivations of ally1 _g~ups have been observed in thermal rearrangements