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Anomalous Reductions of 7-Substituted Norbornadienes with Diimide

โœ Scribed by Baird, William C.; Franzus, Boris.; Surridge, John H.

Book ID
127234159
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
701 KB
Volume
89
Category
Article
ISSN
0002-7863

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Stereoselectivities of mesitonitrile oxi
Stereoselectivities of mesitonitrile oxide cycloadditions to 7-substituted norbornadienes
โœ Lorenzo Dal Bola; Marco De Amici; Carlo De Micheli; Remo Gandolfi; K.N. Houk ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 249 KB

The stereochemistries of cycloadditions of mesitonitrile oxide to norbomadiene and nine 7-substituted derivatives have been investigated. The stereoselectivities are controlled primarily by torsional effects which are altered by 7-substituents.