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Anodic oxidation of ring A-aromatic steroids. Cyanation of the aromatic nucleus

โœ Scribed by Kurt Ponsold; Helmut Kasch

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
164 KB
Volume
20
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The electrochemical oxidation of 3-methoxy-estra-1,3,5(10)triene-17-one I in methanolic sodium cyanide solution leads to rinse Asubstitution products II and III and to the addition product IV. This method represents a new way for the direct introduction of a carbon substituent into position IO of steroids.

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