1,2-Shift in the anodic oxidation of aromatic compounds
β Scribed by Gajanan A. Bhat; Mariappan Periasamy; M. Vivekananda Bhatt
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 125 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The 1,2-shift observed during oxidation of Organic substrates Can arise by inVOlVement of cation radicals.
π SIMILAR VOLUMES
In two recent papers, the anodic oxidation of mercury(II)-olefin complexes in acidic, aqueous solution has been discussed 1'2. These complexes are known to contain a a carbon-mercury bond and it was proposed that the initial step in the oxidation of the complexes to a mixture of carboxylic acids was
The electrochemical oxidation of 3-methoxy-estra-1,3,5(10)triene-17-one I in methanolic sodium cyanide solution leads to rinse Asubstitution products II and III and to the addition product IV. This method represents a new way for the direct introduction of a carbon substituent into position IO of st