✦ LIBER ✦

Mechanisms of steroid oxidation by microorganisms III. Enzymatic mechanism of ring a aromatization

✍ Scribed by Charles J. Sih; A. M. Rahim

Publisher: John Wiley and Sons
Year: 1963
Tongue: English
Weight: 487 KB
Volume: 52
Category: Article
ISSN: 0022-3549
DOI: 10.1002/jps.2600521112

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Mechanism of oxidation of aromatic amine

Mechanism of oxidation of aromatic amines by peroxomonosulphate – a kinetic study

✍ Maddy Satyanarayan Reddy; K. C. Rajanna; Ahmed Naseeruddin 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB

## Abstract Oxidation of aromatic amines (substrate) by peroxomonosulphate (PMS) in phthalate buffers at various temperatures revealed first‐order dependence on [PMS] as well as [Substrate]. Rate of oxidation was found to increase with an increase in pH as well as dielectric constant (D) of the med

Mechanism of Ruthenium (III) Catalysed O

Mechanism of Ruthenium (III) Catalysed Oxidation of L-Valine by Alkaline Hexacyanoferrate (III)

✍ Raj Kishor Shukla 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 35 KB 👁 2 views

## Abstract The kinetics of Ruthenium (III) catalysed oxidation of L‐Valine by alkaline solution of hexacyanoferrate (III) were studied by following the rate of disappearance of Fe(CN)^3‐^. The reaction shows zero order dependence on hexacyanoferrate (III). First order on ruthenium (III). The first

Kinetics and mechanism of oxidation of n

Kinetics and mechanism of oxidation of nitrilotriacetic acid by diperiodatoargentate(III)

✍ Anil Kumar; Paresh Kumar 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 80 KB 👁 2 views

Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.

Kinetics and mechanism of the oxidation

Kinetics and mechanism of the oxidation of glycolaldehyde by tetrachloroaurate(III)

✍ Pratik K. Sen; A. B. Bilkis; Kalyan K. Sen Gupta 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

The kinetics of the reaction between glycolaldehyde (GA) and tetrachloroaurate(III) in acetic acid-sodium acetate buffer has been studied. The reaction is first-order with respect to as well as [GA]. Both and ions retard the rate of reaction. III ϩ Ϫ Ϫ [Au ] H Cl AuCl , 4 and are the reactive specie

Kinetics and mechanism of the oxidation

Kinetics and mechanism of the oxidation of halotoluenes by acidic hexacyanoferrate(III)

✍ A. K. Bhattacharjee; M. K. Mahanti 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB 👁 1 views

## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactants—substrate, oxidant,

Reductive Dissolution of Fe(III) (Hydr)o

Reductive Dissolution of Fe(III) (Hydr)oxides by Cysteine: Kinetics and Mechanism

✍ Aria Amirbahman; Laura Sigg; Urs von Gunten 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 259 KB

Cysteine was used as a model reductant to gain further insight into the kinetics of bacterially mediated iron reduction. Our experimental data and modeling results indicated that the reductive dissolution of hydrous ferric oxide (HFO) takes place via surface complex formation of cysteine and corresp