The electrochemical behaviour of diphenyldiselenide in acetonitrile solution was studied by several electrochemical techniques. Controlled potential electrolysis in the presence of cyclohexene was also studied. The cyclic sweep voltammogram exhibited two irreversible anodic peaks at 1.35 and 1.65 V
Anodic oxidation of heterocumulenes in acetonitrile
β Scribed by Becker, James Y.; Zinger, B.
- Book ID
- 127236595
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 374 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
In an earlier short communication 1 it was reported that the partial electrochemical oxidation of a wide range of aliphatic hydrocarbons is possible in acetonitrile. These oxidations require a high positive potential, and hence the use of a tetrafluoroborate or a hexafluorophosphate as the base elec
The kinetics of the anodic oxidation of ally! alcohol in acetonitrile has been studied. At a platinum electrode at low potentials, ~26 V, the reaction is charge transfer controlled and at higher potentials the process becomes diffusion controlled. The reaction is not a simple charge-transfer process