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Anodic oxidation of alkylated biphenyls. Synthetic routes to certain cyclohexa-1,4-dienes

✍ Scribed by Isidoro Barba; Rafael Chinchilla; Cecilia Gómez


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
116 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The anodic methoxylation of 3-phenyltoluene, 4-phenyltoluene and 4,4'dimethylbiphenyl carried out under constant current intensity afforded a number of new cyclohexa-1,4-dienes.


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A straightforward route to polyols, amino polyols, polysubstituted lactols and lactones from readily available arenes has been devised. It uses a three-or four-step sequence involving a Birch reduction of the arene, followed by desymmetrization through dihydroxylation or aminohydroxylation and, last