Photochemical routes from arenes to inositol intermediates: The photo-oxidation of substituted cis-cyclohexa-3,5-diene-1,2-diols

Short syntheses of conduritols A and D,

Short syntheses of conduritols A and D, and dehydroconduritols, from benzene: The photo-oxidation of cis-cyclohexa-3, 5-diene-1,2-diol

✍ Howard A.J. Carless; Ozer Z. Oak 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 131 KB

YF Diene (l), available by microbial oxidation of benzene, undergoes react on with singlet oxygen to yield endoperoxides (2) and (3); reduction or rearrangement of these compounds gives conduritols ( 5) and ( 6) or dehydroconduritols ( 8) and ( 9), respectively.