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Short syntheses of conduritols A and D, and dehydroconduritols, from benzene: The photo-oxidation of cis-cyclohexa-3, 5-diene-1,2-diol

✍ Scribed by Howard A.J. Carless; Ozer Z. Oak

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 131 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99564-9

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✦ Synopsis

YF Diene (l), available by microbial oxidation of benzene, undergoes react on with singlet oxygen to yield endoperoxides (2) and (3); reduction or rearrangement of these compounds gives conduritols ( 5) and ( 6) or dehydroconduritols ( 8) and ( 9), respectively.

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