Anisotropy of the chemical shift tensor for solid nitrogen
β Scribed by L.M Ishol; T.A Scott
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 400 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
The anisotropy of the chemical shift tensor in solid fluorine has been measured by several independent methods to he (1050\*50} x 10-6. This value is slightl,v smaller than the estimated paramagcetic part of the chemical shift from the spin-rotation constant in the gaseous state.
## Abstract An approach to spinning sideband (SSB) separation of protonated and nonβprotonated carbons in slow spinning conditions via dipolar dephasing is proposed. This method offers two features: SSB spectral simplification, which greatly reduces the overlaps encountered in a usual SSB spectrum,
This paper presents results from applying different point charge models to take into account intermolecular interactions to model the solid state effects on the 15N NMR chemical shifts tensors. The DFT approach with the BLYP gradient corrected exchange correlation functional has been used because it