Anisotropic solvent-induced shifts of the trimethylsiloxy group
β Scribed by J. R. Parsonage; E. A. Vidgeon
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 339 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0749-1581
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## Abstract The chemical shift differences of diastereotopic protons in aliphatic acyclic alcohols, mostly of the type Rο£ΏCH~2~ο£ΏCRβ²Rβ³ο£Ώ(CH~2~)~n~OH, have been investigated. Fairly small amounts of Eu(dpm)~3~ cause the spectra of these materials to simplify dramatically; indeed, even diastereotopic pr
The shifts of Raman band due to solvation effects were measured in various supexcritical fluids which cover a wide density range from gaseous to liquid state. The C==O stretching of acetone and the C=N stretching of acetonitrile were found to be redshifted as the density of fluid increased. The magn