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Anil-Synthese. 24. Mitteilung. über die Herstellung von Styryl- und Stilbenyl-Derivaten des 1H-Benzotriazols

✍ Scribed by Adolf Emil Siegrist


Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
763 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis


Preparation of Styryl and Stilbenyl Derivatives of 1__H__‐Benzotriazoles

1‐(p‐Tolyl)‐substituted 1__H__‐benzotriazoles react with anils of aromatic aldehydes in the presence of dimethylformamide and potassium hydroxide to yield the corresponding 1‐(styr‐4′‐yl)‐1__H__‐benzotriazoles and 1‐(stilben‐4′‐yl)‐1__H__‐benzotriazoles, respectively (‘anil synthesis’). Further, under the same reaction conditions, the Schiff's bases derived from p‐chloroaniline and 4‐(1′H‐benzotriazol‐1′‐yl)benzaldehydes give, with p‐tolyl‐substituted heterocycles, the corresponding heterocyclic substituted stilbenyl derivatives.


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