Anchimerically assisted substitution of a sulfinyl function of α-sulfinylhydrazones by thiols
✍ Scribed by Hubert Bosch; Philippe Pflieger; Charles Mioskowski; Jean-Pierre Salaün; Francis Durst
- Book ID
- 104216122
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 201 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The nitromethane anion reacts with ot-amidoalkyl sulfones in TI-IF affording the corresponding nitro derivatives that upon oxidation with alkaline potassium permanganate give the corresponding N-protected ¢t-araino acids
A New Synthesis of α-Amino Acid Thioesters by Pummerer Reaction of 3-Substituted-4-sulfinyl-β-sultams. -trans-Sultams (I), (V), and (VII), obtained in all cases as two separable epimers at the sulfoxide group, are each converted to the title thioesters via sulfenylation and Pummerer rearrangement w