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Anchimerically assisted substitution of a sulfinyl function of α-sulfinylhydrazones by thiols

✍ Scribed by Hubert Bosch; Philippe Pflieger; Charles Mioskowski; Jean-Pierre Salaün; Francis Durst


Book ID
104216122
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
201 KB
Volume
32
Category
Article
ISSN
0040-4039

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A New Synthesis of α-Amino Acid Thioesters by Pummerer Reaction of 3-Substituted-4-sulfinyl-β-sultams. -trans-Sultams (I), (V), and (VII), obtained in all cases as two separable epimers at the sulfoxide group, are each converted to the title thioesters via sulfenylation and Pummerer rearrangement w