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A New Synthesis of α-Amino Acid Thioesters by Pummerer Reaction of 3-Substituted-4-sulfinyl-β-sultams

✍ Scribed by Iwama, Tetsuo; Kataoka, Tadashi; Muraoka, Osamu; Tanabe, Genzoh


Book ID
120430091
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
95 KB
Volume
63
Category
Article
ISSN
0022-3263

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A New Synthesis of α-Amino Acid Thioesters by Pummerer Reaction of 3-Substituted-4-sulfinyl-β-sultams. -trans-Sultams (I), (V), and (VII), obtained in all cases as two separable epimers at the sulfoxide group, are each converted to the title thioesters via sulfenylation and Pummerer rearrangement w

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