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Analytical Polarization and Coherence Transfer Functions for Three Dipolar Coupled Spins 12

โœ Scribed by Burkhard Luy; Steffen J Glaser


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
223 KB
Volume
142
Category
Article
ISSN
1090-7807

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โœฆ Synopsis


Analytical polarization and coherence transfer functions are presented for a spin system consisting of three dipolar coupled homonuclear spins 1 2 under energy matched conditions. Based on these transfer functions, optimal durations of Hartmann-Hahn mixing periods can be determined for arbitrary dipolar coupling constants D 12 , D 13 , and D 23 . In addition, the dependence of the transfer efficiency on the relative size of the dipolar coupling constants is illustrated.


๐Ÿ“œ SIMILAR VOLUMES


Analytical Polarization and Coherence Tr
โœ Oliver Schedletzky; Burkhard Luy; Steffen J. Glaser ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 224 KB

Analytical polarization and coherence transfer functions are presented for spin systems consisting of three spins 1/2 with arbitrary coupling constants under planar mixing conditions. In addition, simplified transfer functions were derived for symmetric coupling topologies. Based on these transfer f

Superposition of Scalar and Residual Dip
โœ Burkhard Luy; Steffen J Glaser ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 689 KB

The superposition of scalar and residual dipolar couplings gives rise to so-called cylindrical mixing Hamiltonians in dipolar coupling spectroscopy. General analytical polarization and coherence transfer functions are presented for three cylindrically coupled spins 12 under energy-matched conditions