Analytical Polarization and Coherence Transfer Functions for Three Coupled Spins 1/2 under Planar Mixing Conditions
โ Scribed by Oliver Schedletzky; Burkhard Luy; Steffen J. Glaser
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 224 KB
- Volume
- 130
- Category
- Article
- ISSN
- 1090-7807
No coin nor oath required. For personal study only.
โฆ Synopsis
Analytical polarization and coherence transfer functions are presented for spin systems consisting of three spins 1/2 with arbitrary coupling constants under planar mixing conditions. In addition, simplified transfer functions were derived for symmetric coupling topologies. Based on these transfer functions optimal durations for the mixing period can be determined for correlations of interest. Copyright 1998 Academic Press. Copyright 1998 Academic Press
๐ SIMILAR VOLUMES
Analytical polarization and coherence transfer functions are presented for a spin system consisting of three dipolar coupled homonuclear spins 1 2 under energy matched conditions. Based on these transfer functions, optimal durations of Hartmann-Hahn mixing periods can be determined for arbitrary dip
The superposition of scalar and residual dipolar couplings gives rise to so-called cylindrical mixing Hamiltonians in dipolar coupling spectroscopy. General analytical polarization and coherence transfer functions are presented for three cylindrically coupled spins 12 under energy-matched conditions
Analytical coherence transfer functions are presented for spin systems consisting of two spins 1 under planar mixing conditions. Compared to isotropic mixing experiments, larger transfer amplitudes are found and differences in the multiplet patterns are discussed.
On page 176 in Table 2 (d) the coefficients c 1 and c 2 for the transfer from A ฯญ I iz to B ฯญ I iy I jx ฯช I ix I jy should read c 1 ฯญ ฯช 1 6 [1 ฯฉ 2/ อ 3 sin(2 (ki)j )] and c 2 ฯญ ฯช 1 6 [1 ฯช 2/ อ 3 sin(2 (ki)j )]. The corrections do not affect any of the other results given in the paper. The authors th