✦ LIBER ✦

Superposition of Scalar and Residual Dipolar Couplings: Analytical Transfer Functions for Three Spins 1/2 under Cylindrical Mixing Conditions

✍ Scribed by Burkhard Luy; Steffen J Glaser

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 689 KB
Volume: 148
Category: Article
ISSN: 1090-7807
DOI: 10.1006/jmre.2000.2194

No coin nor oath required. For personal study only.

✦ Synopsis

The superposition of scalar and residual dipolar couplings gives rise to so-called cylindrical mixing Hamiltonians in dipolar coupling spectroscopy. General analytical polarization and coherence transfer functions are presented for three cylindrically coupled spins 12 under energy-matched conditions. In addition, the transfer efficiency is analyzed as a function of the relative coupling constants for characteristic special cases.

📜 SIMILAR VOLUMES

Analytical Polarization and Coherence Tr

Analytical Polarization and Coherence Transfer Functions for Three Coupled Spins 1/2 under Planar Mixing Conditions

✍ Oliver Schedletzky; Burkhard Luy; Steffen J. Glaser 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 224 KB

Analytical polarization and coherence transfer functions are presented for spin systems consisting of three spins 1/2 with arbitrary coupling constants under planar mixing conditions. In addition, simplified transfer functions were derived for symmetric coupling topologies. Based on these transfer f