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Analytical Determination of 1,6-Anhydro-β-D-Glucopyranose and Kinetic Studies Under Hydrothermal Conditions

✍ Scribed by Bonn, Guenther


Book ID
115497734
Publisher
Taylor and Francis Group
Year
1985
Tongue
English
Weight
464 KB
Volume
4
Category
Article
ISSN
0732-8303

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Kinetics and mechanism of the acid-catal
✍ Adrie J.J. Straatho; Johannes M. Vrolijk; Herman van Bekkum; Antonius P.G. Kiebo 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 379 KB

The sulfuric acid-catalysed reaction of 1,6-anhydro+D-glucopyranose in lbutanol at SO" gave butyl a-and P-D-glucopyranoside as the sole products. The initial kinetic alp ratio was 1.5, and the final a//3 ratio upon equilibration was 2.7. The four pseudo-first-order reaction rate constants involved h