1H NMR study of 1, 6-Anhydro-β-D-Glucopyranose Tosylated at 2- and/or 4-Position
✍ Scribed by Ronan van Rijsbergen; Marc J. O. Anteunis; André De Bruyn
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 168 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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The 15N NMR spectra of a series of derivatives of 2-amino-2-deoxy-b-D-glucopyranose and dipeptides or secondary amines were recorded. In the dipeptide derivatives the chemical shift of nitrogen atom N-1 (linked to sugar) is essentially unchanged and the shifts of nitrogen atoms N-3 and N-6 are deter
Synthesis and Glycosidic Coupling Reaction of Substituted 2,6-Dioxabicyclo[3.1.1]heptanes: 1,3-Anhydro-2-azido-4,6-di-O-benzyl-2deoxy-β-D-mannopyranose. -The title sugar (VII) is synthesized via the key intermediate (VI) starting from glucopyranoside (I). Anhydrosugar (VII) is quite reactive: ring-