Analytic treatment of the vibronic coupling problem
✍ Scribed by Sighart F. Fischer; Horst Köppel
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 576 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0301-0104
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📜 SIMILAR VOLUMES
## Abstract The influence of linear vibronic coupling on a charge carrier generation resulting from exciton‐exciton scattering is investigated. It is shown that the possibility of dissociation of two excitons into an electron and a hole exists with simultaneous creation of intramolecular phonons. T
hlufrclrai. 8046 Gutclrerg. Ii'csl Gcntrar?y Rcccivcd 7 Iunc 1982 A model consisting of IWO clcctronic shtcs wth drffcrcnl symmctrrcs .md an arbrlrsry number of vtbratrom-d nmh ahh couple thcsc ~131~s ~sconsidcred. Aflcr a scrss of wnomc;ll transformations the hamdloruan IS brought mto a form rulted
The lierzberg-Teller expansion over floating-orbital zero-order w&vefunctions is used to derive vibronic coupling iMegals. These arc shown to be eastly obtained by the use of standard semi-empirical hf0 methods.