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A mixed adiabatic—diabatic representation for the vibronic coupling problem of polyatomic molecules

✍ Scribed by Sighart F. Fischer

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
240 KB
Volume
91
Category
Article
ISSN
0009-2614

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✦ Synopsis

hlufrclrai. 8046 Gutclrerg. Ii'csl Gcntrar?y Rcccivcd 7 Iunc 1982 A model consisting of IWO clcctronic shtcs wth drffcrcnl symmctrrcs .md an arbrlrsry number of vtbratrom-d nmh ahh couple thcsc ~131~s ~sconsidcred. Aflcr a scrss of wnomc;ll transformations the hamdloruan IS brought mto a form rulted IIJ study cffccts of anktrmonic and vlbromc couphngs D~vcrgcnccs typical for non-adrabatrc couplmg terms arc 3vordcd. 1. lnlroduction Electrontc and vlbronlc spectra are usually Interpreted with the help of adiabntx potcntml surfxcs [II

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