Analysis of the enthalpy of solvation in mixed solvents using the Kirkwood-Buff theory. The interplay of preferential solvation and solvent-solvent interactions
✍ Scribed by Enrico Matteoli
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 791 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0167-7322
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Abshact-In order to throw light on ion-solvent interactions, the salvation numbers of electrolytes in different mixed solvents (methanol + water and ethanol + water mixtures) have been determined using ultrasonic interferometer. The anomalies in the salvation number of cations (in aqueous solutions)
## Abstract A study of the correlation of solvent effects on the chemical shifts of the methyl protons of sylvan, toluene and α‐picoline led to the conclusion that the preferential site of solvation of the furan ring in acidic solvents is the π‐electron cloud and not the __n__‐electron orbital of t
Intrarcd spectra ot xctonc m the C=O stretchm, 0 rc~.lon have been studled as a function of the composttion of 3. ran&e of ml\cd prouc-aprotlc solbcnts f-or mcthnollc systems. cqulhbrl:l betv.ecn hydrogen-bonded and non hydrogen-bonded ;Lcctonc dommaw dw spectral chlm~cs. but for aqueous s) stems at
Scaled particle theory was used for calculating the enthalpy of cavity formation in the solvation process of hydroxyl cyclohexane derivatives in water and in organic solvents. From the values calculated for the enthalpy of formation of the cavity and from those quoted for the enthalpy of solvation,