Preferential solvation in mixed solvents. 14. Mixtures of 1,4-dioxane with organic solvents: Kirkwood–Buff integrals and volume-corrected preferential solvation parameters

Thermodynamics of the cell { Li- Amalgam

Thermodynamics of the cell { Li- Amalgam | LiX (m)| AgX | Ag }(X = Cl,Br) and medium effects upon LiX in (acetonitrile  +  water), (1,4-dioxane  +  water), and (methanol  +  water) solvent mixtures with related solvation parameters

✍ Patrizia R. Mussini; ; Torquato Mussini; Barbara Sala 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 291 KB

The electromotive forces E of the amalgam cells {Li x Hg 1-x | LiCl (m) | AgCl | Ag} and {Li x Hg 1-x | LiBr (m) | AgBr | Ag} have been measured as a function of the mole fraction x of Li metal in amalgams and of the molalities m of LiCl as well as LiBr at T = 298.15 K. For LiCl, the solvents invest