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Analysis of Phosphorylated Terpenes by Electrospray Ionization Liquid Chromatography–Tandem Mass Spectrometry

✍ Scribed by Iris Ney; Elke Jäger; Markus Herderich; Peter Schreier; Wilfried Schwab

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
362 KB
Volume
7
Category
Article
ISSN
0958-0344

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✦ Synopsis

Linalool, nerol, geraniol, citronellol and a-terpineol were phosphorylated and the products purified by adsorption chromatography on XAD-2. High performance liquid chromatography-tandem mass spectrometry (LC-MSMS) analysis using the electrospray ionization technique (ESI) revealed the occurrence of mono-, di-, tri-and tetraphosphate esters of the respective monoterpenes. In extracts obtained by XAD-2 adsorption chromatography followed by anion exchange chromatography from green tea leaves, phosphate and diphosphate esters of linalool and cu-terpineol were identified for the first time by ESI LC-MS/MS. The corresponding monoterpene alcohols were analysed by high resolution gas chromatography-mass spectrometry after hydrolysis of the extract using acid phosphatase (EC 3.1.3.2).

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