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Analysis of metal thiourea complexes by chloramine-T oxidation

✍ Scribed by D. K. Padma; A. R. Vasudeva Murthy

Publisher
Springer
Year
1970
Tongue
English
Weight
227 KB
Volume
58
Category
Article
ISSN
0026-3672

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πŸ“œ SIMILAR VOLUMES

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## Abstract The formation of palladium(II) complexes with aliphatic amines and their oxidation by chloramine‐T in perchloric acid medium has been studied. The spectrophotometric studies showed the formation of 1:1 and 1:2 complexes between palladium(II) and amine in absence of HClO~4~. An increase

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## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t