Semimicro determination of selenium and tellurium by chloramine-T oxidation
β Scribed by Padma, D. K. ;Shaw, R. A. ;Murthy, A. R. Vasudeva ;Woods, M.
- Publisher
- Springer-Verlag
- Year
- 1974
- Weight
- 162 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0344-838X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramineβT (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is β__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t
Oxidations of indigocarmine (IC) by chloramine-T (CAT) and aqueous chlorine (HOC1) in acidic buffer media, pH 2-6, have been kinetically studied at 30Β°C using spectrophotometry. The CAT reaction rate shows a first-order dependence on [IClo and an inverse fractional order on [p-toluenesulfonamidel. T
## Abstract The formation of palladium(II) complexes with aliphatic amines and their oxidation by chloramineβT in perchloric acid medium has been studied. The spectrophotometric studies showed the formation of 1:1 and 1:2 complexes between palladium(II) and amine in absence of HClO~4~. An increase